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Ready; Catalysis Isomerization/cyclization-1 R M R' M R R' H R R' M H MH R R' H R' M M H Olefin insertion into Metal alkyl can be followed by hydride elimination or additional olefin insertions: -dimerization/oligomerization -small molecules -polymerization Recall: electron rich M (late transition metal) Keq < 1 ->dimerization, etc electron poor M (early transition metal) Keq > 1 ->polymerization P Ph2 Ni OO H C7-C14 C1-C3 HO C10-C18 C1-C3 C7-C14 Shell

Herz Lab publications

1 Kinetic Resolutions Material outline: For the Scientist in you: Definitions Theoretical treatment For the technician in you: Practical considerations Useful KR’s Oxidative KR of allylic alcohols An extreme example Acylation/deacylation Hydrogenation olefins ketones Dynamic kinetic resolution Epoxide ring opening A very extreme example Parallel kinetic resolution General References: Vedejs, ACIEE, 2005, 3974 Jacobsen, Adv. Syn

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Handbook for Postdoctoral Scholars at UT Southwestern Postdoctoral Affairs Office UT Southwestern Medical Center 5323 Harry Hines Blvd. Dallas, TX 75390-9004 SGSPostdocOffice@UTSouthwestern.edu www.utsouthwestern.edu/Postdocs mailto:SGSPostdocOffice@UTSouthwestern.edu http://www.utsouthwestern.edu/Postdocs dbrekk Typewriter https://www.utsouthwestern.edu/edumedia/edufiles/graduate_school/postdoctoral_scholars/handbook.pdf 1 TABLE OF CONTENTS Welcome! 欢迎

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Volunteers Needed For Clinical Research at UT Southwestern. We are conducting studies in obesity, heart disease risk, and type 2 diabetes risk in adults. Please contact us at (214) 648-9014. Compensation available for some studies. For more information please call - 214-648-9014

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© U T So ut hw es te rn M ed ic al C en te r, 20 11 . M KT 8 96 _0 3 Qualified participants must be: • Between age 18–70 years • South Asian or European Americans • Male and Female • Able to attend two visits • �Persons taking medications for diabetes, heart disease or chronic health issues may not qualify For more information 214.648.9014 Are you interested in research on body fat?

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