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DOI: 10.1021/la904597c 4563Langmuir 2010, 26(7), 4563–4566 Published on Web 02/24/2010 pubs.acs.org/Langmuir © 2010 American Chemical Society Infrared Characterization of Interfacial Si-O Bond Formation on Silanized Flat SiO2/Si Surfaces Ruhai Tian,†,‡ Oliver Seitz,§ Meng Li, ) Wenchuang (Walter) Hu,‡ Yves J. Chabal,§ and Jinming Gao*,† †Department of Chemistry, ‡Department of Electrical Engineering, and §Department of Materials Science and Engineering, University of Texas at Dallas

1 P(tBu)2 P(tBu)2 CuBr P Pd P P P PBu3 Pt H Et3P Cl PEt3 Ir S R3P H PR3 H S -S PF6 - Ir S R3P H PR3 H P P Pd PF6 - Pt H Et3P Cl PEt3 Py P P Ir S R3P H PR3 H PF6 - Pt H Et3P Py PEt3 Cl Fe Pt H Et3P Py PEt3 P P Cl- Organometallic Reaction Mechanisms Ligand association/dissociation + toluene insoluble (PBu3)nCuBr soluble + active catalyst for cross coupling = NOTE: No ox. state change Ligand Exchange: Associative - common for 16e- complexes

Original Research In vivo angiogenesis imaging of solid tumors by avb3-targeted, dual-modality micellar nanoprobes Chase W Kessinger1, Chalermchai Khemtong1, Osamu Togao2, Masaya Takahashi2, Baran D Sumer3 and Jinming Gao1 1Department of Pharmacology, Harold C Simmons Comprehensive Cancer Center; 2Advanced Imaging Research Center; 3Department of Otolaryngology, University of Texas Southwestern Medical Center at Dallas, ND2.210, 5323 Harry Hines Boulevard, Dallas, TX 75390, USA

1 Ready; Catalysis Hydrogenation Categories and Dichotomies: Heterogeneous or Homogeneous Neutral or Cationic Directed or Non-directed Heterolytic or Homolytic H2 Activation Racemic or Enantioselective Syn or Trans Addition Homogeneous Hydrogenation Rh Ph3P Ph3P Cl PPh3 Advantages: Mild conditions Improved selectivity Directed Hydrogenation Enantioselective Hydrogenation Mechanistically accessible Disadvantages: Purification $$$$ Often less

Lithographically defined uniform worm-shaped polymeric nanoparticles This article has been downloaded from IOPscience. Please scroll down to see the full text article. 2010 Nanotechnology 21 095301 (http://iopscience.iop.org/0957-4484/21/9/095301) Download details: IP Address: 129.112.109.250 The article was downloaded on 14/10/2010 at 15:22 Please note that terms and conditions apply. View the table of contents for this issue, or go to the journal homepage for more Home Search

1 R Co(CO)3(OC)3Co O O Δ (OC)3Co O R H O R H2 R H O (OC)4Co R (OC)4Co Co(CO)4 H H (CO)4CoH H2 CO R O H R CO (OC)3Co R (OC)3Co H R H2 R (OC)3Co R The Oxo process -developed in 1938 by Otto Roelen -Principle method for hydroformylation of terminal alkenes industrially -more that 4 million tons aldehyde annually -linear aldehydes more desirable Co2(CO)8 H2/CO (200-300 atm) 120-170 oC linear (normal) branched (iso) + chemical feed stocks linear alcohols

Dynamic Article LinksC<Lab on a Chip Cite this: Lab Chip, 2011, 11, 1952 www.rsc.org/loc PAPER D ow nl oa de d by U ni ve rs ity o f T ex as a t D al la s on 0 3 Ju ly 2 01 1 Pu bl is he d on 1 9 A pr il 20 11 o n ht tp :// pu bs .r sc .o rg | do i:1 0. 10 39 /C 0L C 00 60 5J View Online Ultrasensitive protein detection using lithographically defined Si multi- nanowire field effect transistors† Ruhai Tian,ab Suresh Regonda,a Jinming Gao,b

Ready; Catalysis Isomerization/cyclization-1 R M R' M R R' H R R' M H MH R R' H R' M M H Olefin insertion into Metal alkyl can be followed by hydride elimination or additional olefin insertions: -dimerization/oligomerization -small molecules -polymerization Recall: electron rich M (late transition metal) Keq < 1 ->dimerization, etc electron poor M (early transition metal) Keq > 1 ->polymerization P Ph2 Ni OO H C7-C14 C1-C3 HO C10-C18 C1-C3 C7-C14 Shell

Journal of Controlled Release 151 (2011) 271–277 Contents lists available at ScienceDirect Journal of Controlled Release j ourna l homepage: www.e lsev ie r.com/ locate / jconre l N A N O M E D IC IN E Nanoscopic micelle delivery improves the photophysical properties and efficacy of photodynamic therapy of protoporphyrin IX Huiying Ding a, Baran D. Sumer c, Chase W. Kessinger a, Ying Dong a,b, Gang Huang a, David A. Boothman a,b, Jinming Gao a,⁎ a Department of Pharmacology, University of

Advanced Synthesis and Catalysis, 2006 Unless noted, class is 9:00-10:30, mon and wed, L4.14 Date Topic Lecturer 8-22 Intro to catalysis Ready 8-24 Organometallics: structure/reactivity-1 Ready 8-29 Organometallics: structure/reactivity-2 Ready 8-31 Kinetics and mech-1 Ready 9-5 Kinetics and mech-2 Ready 9-7 Kinetic resolutions Ready 9-12 Nonlinear effects Ready 9-14 Addns to pi bonds-1 Ready 9-19 Addns to pi bonds-2 Ready 9-21 Addns to pi bonds-3 Ready 9-26 Conjugate addition-1 Ready 9-28