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Substrate pKa's. Numbers are approximations for outside the range -2 - 16, but useful to know. For an extensive list, see http://www.chem.wisc.edu/areas/reich/pkatable/ Inorganics H2O DMSO CF3SO3H -14 HCl -8 H3O+ -2 H2O 16 NH4Cl 9 Organic X-H AcOH 5 12 O+ CH3Ph H -6 Me2OH+ -4 CH3SO3H -3 2 NH+ 5 3 N H O H 15 26 MeOH 16 28 17 29 NH3 36 38 41 EWG-CH NO2-CH3 10 17 O O 9 13 O EtO O 11 14 O EtO OEt O 13 16 O 20 27 O t-BuO 25 30 O Me2N 35 O S 3533PhOH 10 18

ll Matter of Opinion Young martlets: Exploring the world of academia and beyond Zhen Yin,1,2,* Bihe Chen,1,* Xiangkun Elvis Cao,1,3 Binbin Ying,1,4,5 Haocheng Quan,1,6 Chonghe Wang,1,7 Yinyin Ye,1,8 Xiaocheng Mi,1,4 Chian Yan,1,9 Yudi Ding,1,10 Shiming Zhang,1,11 Aram Bahmani,1,4 Ahmed Dalaq,1,12,13 Xiaotong Li,1,14 Xiao Shang,1,4,5 Kewang Nan,1,15 and Yiran Yang1,16 The Martlets Society (www.martlets-society.com) is an independent non-profit organization found and run by young scholars. It

Ready; Catalysis Nonlinear Effects Outline Definitions Origins of nonlinear effects in enantioselective reactions ML2 model Reservoir model Transition-state model Kinetic aspects of nonlinear effects Asymmetric amplification Cool tricks Origin of biotic asymmetry? Key reviews Kagan, ACIEE, 1998, 2922 (a pretty complete review, source of many of my figures) Kagan, Advanced Syn. Cat., 2001, 227 (an overview) Blackmond, Accts, 2000, 402 (kinetic aspects) Soai

RESEARCH ARTICLE www.mbs-journal.de Toward Highly Matching the Dura Mater: A Polyurethane Integrating Biocompatible, Leak-Proof, and Self-Healing Properties Pandi Chen, Fenglong Li, Guyue Wang, Binbin Ying, Chao Chen, Ying Tian, Maosong Chen, Kyung Jin Lee, Wu Bin Ying,* and Jin Zhu* The dura mater is the final barrier against cerebrospinal fluid leakage and plays a crucial role in protecting and supporting the brain and spinal cord. Head trauma, tumor resection and other traumas damage it

Resourses Collaborating Facilities at UT Southwestern Core Facilities Centers and Institutes Advanced Imaging Research Center (AIRC) Cecil H. and Ida Green Comprehensive Center for Molecular, Computational, and Systems Biology Cecil H. and Ida Green Center for Reproductive Biology Sciences Center for Alzheimer's and Neurodegenerative Diseases Center for the Genetics of Host Defense Center for Human Nutrition Center for Translational Medicine Center for Translational Neurodegeneration Research

1 Kinetic Resolutions Material outline: For the Scientist in you: Definitions Theoretical treatment For the technician in you: Practical considerations Useful KR’s Oxidative KR of allylic alcohols An extreme example Acylation/deacylation Hydrogenation olefins ketones Dynamic kinetic resolution Epoxide ring opening A very extreme example Parallel kinetic resolution General References: Vedejs, ACIEE, 2005, 3974 Jacobsen, Adv. Syn

#!/usr/bin/perl     open(FILE1,  "Input.fastq")  or  die("Unable  to  open  file");   open(OUTPUT,  ">Output.fastq")  or  die("Unable  to  open  file");   use  strict;     my  $line;   my  @line;   my  $line1;   my  $seq0;   my  $junk;   my  $qual0;   my  $qual;   my  $seq;   my  $base;   my  $rest;   my  $newline;   my  @newline;   my  $n=1;   my  $m=1;   my  $newscore;   my  $restscore;   my

Cite the UT Southwestern NORC The National Institutes of Health requires that investigators cite our grant in all publications, posters, press releases, proposals, abstracts and/or presentations resulting from the use of any of our cores’ services. Our productivity and effectiveness as a Center is measured in part by the citation of the grant in your published work. Please acknowledge National Institutes of Health grant P30DK127984 in all publications resulting from the use of our cores

1 Ready; Catalysis Kinetics-1 There are only two important things in chemistry, kinetics and thermodynamics. And, exp(-ΔG/RT) = k1/k-1, so there’s really only one thing. Kinetics provides information about the transition state of a reaction. We’ll use a simple example to learn the basic tools, then look at more applications to catalysis. Crude Data [EtI] = [NaCN] 0 0.2 0.4 0.6 0.8 1 1.2 0 2 4 6 8 10 Time Co nc en tra tio n [EtI] [EtCN] 1st step

L E C T U R E S E R I E S CARDIOMETABOLIC Dr. Vaduganathan received his medical degree from Northwestern University, where he also obtained a master’s degree of public health. He completed residency training at Massachusetts General Hospital and fellowship training in cardiovascular medicine at Brigham and Women’s Hospital. His research is centered on drug development, clinical trials, and the implementation of cardio-renal-metabolic therapies. Dr. Vaduganathan has authored or co-authored