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1 Ready; Catalysis Hydrogenation Categories and Dichotomies: Heterogeneous or Homogeneous Neutral or Cationic Directed or Non-directed Heterolytic or Homolytic H2 Activation Racemic or Enantioselective Syn or Trans Addition Homogeneous Hydrogenation Rh Ph3P Ph3P Cl PPh3 Advantages: Mild conditions Improved selectivity Directed Hydrogenation Enantioselective Hydrogenation Mechanistically accessible Disadvantages: Purification $$$$ Often less

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1 R Co(CO)3(OC)3Co O O Δ (OC)3Co O R H O R H2 R H O (OC)4Co R (OC)4Co Co(CO)4 H H (CO)4CoH H2 CO R O H R CO (OC)3Co R (OC)3Co H R H2 R (OC)3Co R The Oxo process -developed in 1938 by Otto Roelen -Principle method for hydroformylation of terminal alkenes industrially -more that 4 million tons aldehyde annually -linear aldehydes more desirable Co2(CO)8 H2/CO (200-300 atm) 120-170 oC linear (normal) branched (iso) + chemical feed stocks linear alcohols

Skip to main content News June, 2024 Congratulations to Magda on her new publication. Testis Specific Serine Kinase 6 (TSSK6) is abnormally expressed in colorectal cancer and promotes oncogenic behaviors View Article November, 2023 Congratulations to Luis on his new publication. The cancer testes antigen, HORMAD1, limits genomic instability in cancer cells by protecting stalled replication forks. View Article September, 2023 Congratulations to Luis on starting his new post doc position. Arnab

Ready; Catalysis Intro Helpful Texts: Principles and Applications of Organotransition Metal Chemistry, Collman, Hegedus, Norton, Fink The Organometallic Chemistry of the Transition Metals, Crabtree; Prof. M-Christina White’s lecture notes: http://www.courses.fas.harvard.edu/~chem153/ (many of my notes are taken from these, with permission) Advanced Synthesis and Catalysis, Spring 2011 Or: How to make more molecules more complex more quickly with less effort/material/waste

Skip to main content Funding Our research is supported by both government agencies and private foundations: National Cancer Institute Mary Kay Research Foundation Stand Up 2 Cancer Watch SU2C's video about Dr. Whitehurst Uniting Against Lung Cancer JimmyV Foundation Golfers Against Cancer (Greensboro, N.C.) Department of Defense Lung Cancer Research Program UTSW Friends of the Comprehensive Cancer Center 1 Million 4 Anna Foundation St. Baldrick's Foundation Join Our Lab Be part of the great

1 P(tBu)2 P(tBu)2 CuBr P Pd P P P PBu3 Pt H Et3P Cl PEt3 Ir S R3P H PR3 H S -S PF6 - Ir S R3P H PR3 H P P Pd PF6 - Pt H Et3P Cl PEt3 Py P P Ir S R3P H PR3 H PF6 - Pt H Et3P Py PEt3 Cl Fe Pt H Et3P Py PEt3 P P Cl- Organometallic Reaction Mechanisms Ligand association/dissociation + toluene insoluble (PBu3)nCuBr soluble + active catalyst for cross coupling = NOTE: No ox. state change Ligand Exchange: Associative - common for 16e- complexes

Skip to main content Contact Us Get in Touch Angelique Whitehurst, Ph.D. Office Phone: 214-645-6066 Lab Phone: 214-645-6094 Email Address UT Southwestern Medical Center 6001 Forest Park Road, ND7.124B Dallas, TX 75390-9041 Get directions

2010 | Mater. Horiz., 2024, 11, 2010–2020 This journal is © The Royal Society of Chemistry 2024 Cite this: Mater. Horiz., 2024, 11, 2010 Kirigami-enabled stretchable laser-induced graphene heaters for wearable thermotherapy† Junyu Chen,‡ab Yichao Shi,§a Binbin Ying, ¶ac Yajie Hu,b Yan Gao,b Sida Luo *b and Xinyu Liu *ad Flexible and stretchable heaters are increasingly recognized for their great potential in wearable thermotherapy to treat muscle spasms, joint injuries and arthritis

Skip to main content Publications Sperm-specific COX6B2 enhances oxidative phosphorylation, proliferation, and survival in human lung adenocarcinoma. Cheng CC, Wooten J, Gibbs ZA, McGlynn K, Mishra P, Whitehurst AW, 2020 Sep Elife 9 The testis protein ZNF165 is a SMAD3 cofactor that coordinates oncogenic TGF? signaling in triple-negative breast cancer. Gibbs ZA, Reza LC, Cheng CC, Westcott JM, McGlynn K, Whitehurst AW, 2020 Jun Elife 9 HORMAD1 is a negative prognostic indicator in lung